"I guess I'm gonna be a dad with a lot of kids," he said at the time.
WATCH: Report Claims Brad Pitt Is Under Investigation for Alleged Incident Involving His Child Brad Pitt and Jennifer Aniston, 1998-2005 , he was still married to Aniston.
The two said "I do" in Malibu, California, in 2000, after dating since 1998 when they were set up on a blind date by both of their agents.
"I think of [Jonny] when I think of that [film]," she dished.
"Although, I'm sure the movie looks so ancient now, but we had a lot of fun making that." Brad Pitt and Robin Givens, 1986-1987 co-star.
Unfortunately, things didn't work out and they ultimately called it quits.
According to an interview Jolie did with in May 2014, the two are still "great" friends.